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For a wonderful spicy vinegar, combine peppercorns, cloves, gingerroot and a red chili pepper with 2 cups of balsamic vinegar into a quart jar. Place plastic wrap on top before putting on the metal top to prevent erosion of the metal. STore in a dark place for 2 weeks, shaking every few days. Strain and pour into sterilized bottles. Add a bit of fresh herbs for an attractive decoration. Use within 6 months.